Year: 2025
Type: article
Abstract: Organic–inorganic hybrid halide perovskites have attracted attention in optoelectronics and photovoltaics. However, the Pb-content in the crystal structure and instability issues have raised questions about the industrialization of these materials. Bi and Sb are widely considered as an alternative on the B-site due to their isoelectronic configuration with the Pb divalent cation. Herein, we report four novel Pb-free azetidinium metal halides and present their fundamental material properties: [(CH2)3NH2]2AgBiBr6, [(CH2)3NH2]3Bi2I9, [(CH2)3NH2]3Bi2Br9, and [(CH2)3NH2]3Bi2Cl9. Our materials have a low-dimensional perovskite-like structure from 0 to 2D, where the replacement on the B-site is based on Ag+/Bi3+ and Bi3+. Graphical Abstract As a potential light absorber, four different azetidinium metal halides were successfully synthesized via evaporation. The polycrystalline powders and thin films of the azetidinium metal halides present low dimensionalities from 0 to 2D.
Source: MRS Communications
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,390
Awards: CICECO-Instituto de Materiais de Aveiro, G1685465502, G1792064735, G1918496035, G3592153812, CICECO – Instituto de Materiais de Aveiro, G538229566, Dielektrische Effekte in Hybrid Perovskiten und Ladungsselektive Charakterisierung von Ladungsträgerfallen, CICECO-Instituto de Materiais de Aveiro, Structural distortions and ferroic orders in solids with 3-D and 2-D oxygen octahedral networks: crystallophysical approach to development of new multifunctional materials, G7148304117, G917233707
OpenAlex ID: W4410359701