Work

Arrangement of σ-holes at the halogen atom in halonium cations

Year: 2025

Type: article

Abstract: cations revealed that altering the values of the C⋯X⋯C angles leads to the following consequences: two σ-holes can merge into a single belt-like region, or they may both disappear entirely. The unusual fluctuations in the distribution of σ-holes caused by such geometry maneuvering were observed.

Source: Physical Chemistry Chemical Physics

DOI: 10.1039/d5cp00703h

Authors: Mariusz Michalczyk, Wiktor Zierkiewicz

Institution: Wrocław University of Science and Technology

Language: English

Topic: Crystallography and molecular interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funder: Politechnika Wrocławska

OpenAlex ID: W4410376341

FWCI: 2.256

Cites: 64

Cited by: 5

Related to: 10