Work

Chiral PCN pincer Ni( ii ) complex-catalyzed asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine

Year: 2025

Type: article

Abstract: N, various 2-alkenoylpyridines reacted smoothly with diphenylphosphine to afford structurally diverse chiral pyridine-containing phosphine derivatives in yields up to 99% with an enantioselectivity up to 98% ee. Further transformations of the catalysis products were also studied.

Source: RSC Advances

DOI: 10.1039/d5ra01336d

Authors: Jin-Ge Li, Bing-Bo Qiu, Hui Jiang, Mao-Ping Song, Jun-Fang Gong

Institution: Zhengzhou University

Language: English

Topic: Organophosphorus compounds synthesis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,042

Funder: National Natural Science Foundation of China