Work

Enhanced Photoelectrochemical Water Splitting Using a NiFe2O4/NG@MIL-100(Fe)/TiO2 Composite Photoanode: Synthesis, Characterization, and Performance

Year: 2025

Type: article

Abstract: NiFe2O4 and TiO2 are widely studied for photoelectrochemical (PEC) applications due to their unique properties. Nitrogen-doped graphene (NG) and metal–organic frameworks (MOFs), such as MIL-100(Fe) (where MIL stands for Materials of Lavoisier Institute), are commonly incorporated to enhance PEC performance by offering a high surface area and facilitating efficient charge transport. Composite systems are commonly employed to overcome the limitations of individual PEC catalysts. In this study, a highly efficient NiFe2O4/NG@MIL-100(Fe)/TiO2 photoanode was developed to enhance photoelectrochemical water-splitting performance. The composite was synthesized via a hydrothermal method with a two-step heating process. X-ray diffraction confirmed the expected crystal structures, with peak broadening in NiFe2O4 indicating reduced crystallite size and increased lattice strain. X-ray photoelectron spectroscopy of the Ni 2p and Fe 2p regions validated the successful integration of NiFe2O4 into the composite. Electrochemical analysis demonstrated excellent performance, with linear sweep voltammetry achieving a peak photocurrent density of 3.5 mA cm−2 at 1.23 V (vs RHE). Electrochemical impedance spectroscopy revealed a reduced charge-transfer resistance of 50 Ω, indicating improved charge transport. Optical and electronic properties were evaluated using UV-Vis spectroscopy and Tauc plots, revealing a direct bandgap of 2.1 eV. The composite exhibited stable photocurrent under amperometric J-t testing for 2000 s, demonstrating its durability. These findings underscore the potential of NiFe2O4/NG@MIL-100(Fe)/TiO2 as a promising material for renewable energy applications, particularly in photoelectrochemical water splitting.

Source: Journal of Composites Science

DOI: 10.3390/jcs9050250

Authors: Waheed Rehman, Faiq Saeed, Samia Arain, Muhammad Usman, Bushra Maryam, Xianhua Liu

Institutions: Tianjin University, Chulalongkorn University

Language: English

Topic: Advanced Photocatalysis Techniques

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $2,172