Stepwise Reactions in the Potassium and Ammonia-Intercalated Iron Selenide Superconductor Phase Diagram Followed by In Situ Powder Diffraction
Year: 2025
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide Iron-based superconductors have attracted much attention for their high superconducting temperatures and high upper critical fields, which make them promising candidates for application as well as fundamentally important for our understanding of superconductivity. One feature of these superconductors is their ability to intercalate and deintercalate species from between their iron-containing layers, something not available in cuprate high-temperature superconductors or niobium-based conventional superconductors used in technologies. This provides an opportunity for switchable changes in the superconducting properties as a function of chemical conditions, but the resulting structures are often hard to characterize due to loss of crystallinity and sometimes the formation of multiphase products. Here, we explore both the synthesis and decomposition of potassium and ammonia-intercalated iron selenide superconductors through in situ powder X-ray diffraction. We report a complete phase diagram including two new solution-stable ammonia-rich phases and several metastable forms. We give accurate characterization of the reported ammonia-poor forms using a combination of neutron and X-ray powder diffraction, using an innovative supercell approach to describe the phase breadth within the samples. These results give rare insight into stepwise changes occurring in solids along multiple reaction pathways, which demonstrate the importance of in situ diffraction techniques.
DOI: 10.1021/jacs.5c00356
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
Awards: A SQUID Magnetometer for Quantum Materials, superconductors, molecular magnets and excited states, The Complexity Revolution: Exploiting Unconventional Order in Next-Generation Materials Design, G5103647347, Oxford Quantum Materials Platform Grant, Exploiting the anion Chemistry of solids for Future Advanced Functional Materials: Core-to-Core Project on Mixed Anion Research for Energy Conversion, New approaches to iron-based superconductors, Soft chemical control to achieve new layered architectures and strongly correlated states.
OpenAlex ID: W4410488170