Work

Photoexcited and ground-state diradical(oid) character in a triquino[3]radialene

Year: 2025

Type: article

Abstract: Triquino[3]radialene (R = t Bu) has a photoaccessible triplet state, assigned by TA spectroscopy and CIPT2 calculations. The ground- and excited-states have global magnetically-induced ring currents according to calculations.

Source: Chemical Science

DOI: 10.1039/d5sc01676b

Authors: Bethany K. Hillier, Damon M. de Clercq, Stephen D. S. Bortolussi, Simona S. Capomolla, Michael P. Nielsen, Katarzyna Młodzikowska-Pieńko, Renana Gershoni-Poranne, Timothy W. Schmidt, Martin D. Peeks

Institutions: UNSW Sydney, Technion – Israel Institute of Technology

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Australian Nuclear Science and Technology Organisation, National Computational Infrastructure, Australian Government, Australian Synchrotron, University of New South Wales, Israel Science Foundation, Australian Research Council, National Cancer Institute

Awards: G3498338810, Pushing the limits of electronic delocalization in organic molecules, Charge and Energy Transfer Processes at Inorganic-Organic Interfaces , G8578170565

OpenAlex ID: W4410513831

FWCI: 1.192

Cites: 61

Cited by: 4

Related to: 10