Work

Copper‐Photoredox‐Catalyzed C(sp 3 )–C(sp 3 ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents

Year: 2025

Type: article

Abstract: Herein, we report a reductive cross‐coupling reaction of bicyclo[1.1.1]pentyl (BCP)‐thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photoredox catalyst system. The approach is the first example of a cross‐coupling between BCP‐based reagents with alkyl electrophiles.

Source: Angewandte Chemie

DOI: 10.1002/ange.202506785

Authors: Saikat Pandit, Tobias Ritter

Institutions: Max-Planck-Institut für Kohlenforschung, RWTH Aachen University

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $5,790

OpenAlex ID: W4410518738

FWCI: 0.596

Cites: 47

Cited by: 2

Related to: 10