Work

Copper‐Photoredox‐Catalyzed C(sp 3 )–C(sp 3 ) Reductive Cross‐Coupling of Alkyl Bromides with BCP‐Thianthrenium Reagents

Year: 2025

Type: article

Abstract: Herein, we report a reductive cross-coupling reaction of bicyclo[1.1.1]pentyl (BCP)-thianthrenium reagents and alkyl bromides. The reaction is catalyzed by a copper/photoredox catalyst system. The approach is the first example of a cross-coupling between BCP-based reagents with alkyl electrophiles.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.202506785

Authors: Saikat Pandit, Tobias Ritter

Institutions: Max-Planck-Institut für Kohlenforschung, RWTH Aachen University

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $5,510

OpenAlex ID: W4410531014

FWCI: 5.065

Cites: 47

Cited by: 17

Related to: 10