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Computational and experimental evidence for Sb( v ) metal mediated C–H activation and oxidative functionalization of arenes

Year: 2025

Type: article

Abstract: Quantum-chemical calculations and experiments demonstrated that inorganic Sb V complexes can directly activate aromatic sp 2 C–H bonds and induce oxidative functionalization to form aryl esters.

Source: Chemical Science

DOI: 10.1039/d5sc02048d

Authors: Anjaneyulu Koppaka, Shu-Sen Chen, Dongdong Yang, Artem Marchenko, Sanaz Mohammadzadeh Koumleh, David J. Michaelis, Roy A. Periana, Daniel H. Ess

Institutions: Brigham Young University, University of Florida, The Herbert Wertheim UF Scripps Institute for Biomedical Innovation & Technology

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: U.S. Department of Energy, Brigham Young University, Office of Science, Basic Energy Sciences

Awards: G1397064980, THEORY OF MAIN-GROUP, P-BLOCK HYDROCARBON FUNCTIONALIZATION REACTIONS

OpenAlex ID: W4410547916

FWCI: 0.596

Cites: 37

Cited by: 2

Related to: 10