Work

Streamlined physical activation of Pistacia terebinthus shells: carbonization and activation kinetic studies

Year: 2025

Type: article

Abstract: This study examines the physical activation of Pistacia terebinthus shells—an underutilized biomass—using CO 2 and H 2 O, highlighting a single-reactor, energy-efficient process that eliminates intermediate cooling and reheating, reducing energy consumption by ∼30 %. Activation temperature (700–900 °C), carbonization temperature (300–500 °C), and activating agent concentration (volume ratio of activating gas to inert carrier, 1:4 to 4:1) were optimized for porosity and yield. Steam activation at 800 °C (H 2 O:N 2 = 1:1) produced the highest surface area (1173 m 2 /g) and mesoporosity (70 %), outperforming CO 2 activation, which favored microporosity. Carbonization kinetics, modeled using the Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) methods, exhibited a two-phase activation energy trend over the conversion range of 0.10–0.45. Activation kinetics followed a zero-order model, with H 2 O exhibiting a lower activation energy (64.8 kJ/mol) than CO 2 (117.2 kJ/mol), indicating higher reactivity. • Streamlined activation by removing excess cooling and reheating, saving 30 % energy. • H 2 O activation boosts mesopores and surface area, while CO 2 favors microporosity. • Activation energy in carbonization drops then rises, indicating structural change. • H 2 O's lower activation energy indicating steam's higher reactivity with carbon. • Pistacia terebinthus shells: a novel renewable source for active carbon production.

Source: Biomass and Bioenergy

DOI: 10.1016/j.biombioe.2025.108010