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The impact of second coordination sphere functional group extension on product selectivity for manganese bipyridyl CO 2 reduction electrocatalysts

Year: 2025

Type: article

Abstract: Four new Mn polypyridyl complexes are studied to probe the influence of distal, outer coordination sphere, H-bonding and steric effects on CO vs. HCO 2 − vs. H 2 product selectivity during the proton-coupled electrocatalytic reduction of CO 2 .

Source: Dalton Transactions

DOI: 10.1039/d5dt00157a

Authors: Lisa Suntrup, Vanna Blasczak, Roonak Saeedi, Mehmed Z. Ertem, Jonathan Rochford

Institutions: University of Massachusetts Boston, Brookhaven National Laboratory

Language: English

Topic: CO2 Reduction Techniques and Catalysts

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

Open Access status: hybrid