Work

Stimulus-responsive metallocenes: a photo/thermal switch enabled by the perfluorinated Cp* ligand

Year: 2025

Type: article

Abstract: ] a thermally induced backreaction to ruthenocene is observed. This represents the first example of a reversible dissociation and recoordination of a cyclopentadienyl ligand, initiated by light and heat.

Source: Chemical Science

DOI: 10.1039/d5sc02784e

Authors: Robin Sievers, Nick Hartmann, Paulin S. Riemann, Tim-Niclas Streit, Moritz Malischewski

Institution: Freie Universität Berlin

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Fonds der Chemischen Industrie, Deutsche Forschungsgemeinschaft, Freie Universität Berlin

Awards: G3645873082, SFB 1349: FluorSpezifische Wechselwirkungen: Grundlagen und Anwendungen

OpenAlex ID: W4410790061

FWCI: 0.585

Cites: 48

Cited by: 2

Related to: 10