Work

Preparation and Optimization of NiFe2O4/GAC Composite Catalyst and Its Application in PEM Electrolytic Ozonation for Sulfamethoxazole Degradation

Year: 2025

Type: article

Abstract: With the increasing detection of antibiotics such as sulfamethoxazole (SMX) in water bodies, developing efficient and eco-friendly treatment technologies is critical. This study employs a hydrothermal impregnation method to prepare a NiFe2O4/granular activated carbon (GAC) composite catalyst, optimized for use in a proton exchange membrane (PEM) electrolytic ozonation system to degrade SMX. Single-factor experiments optimized preparation conditions with a Fe:Ni molar ratio of 3:1, a GAC:Fe + Ni mass ratio of 2:1, and calcination at 500 °C for 3 h. The catalyst was characterized using XRD, SEM, TEM, XPS, and FT-IR, confirming a spinel NiFe2O4 structure (crystal size ~15.2 nm) uniformly dispersed on GAC, with an Fe:Ni atomic ratio of ~2.1:1. In the PEM system, the optimized catalyst achieved a 99.15% ± 0.3% SMX degradation rate (50 mg/L) within 25 min, compared to 95.06% ± 0.6% in 30 min without a catalyst. The catalyst maintained 98.45% ± 0.5% efficiency after three cycles, demonstrating excellent stability. The synergy between GAC adsorption and NiFe2O4 catalysis, driven by Fe3+/Fe2+ redox cycling, enhances ·OH generation from ozone decomposition, boosting SMX degradation. This work provides a robust catalyst for antibiotic wastewater treatment and a foundation for scaling up catalytic ozonation.

Source: Coatings

DOI: 10.3390/coatings15060654

Authors: Xiaohong Xu, Bo Wen, Yu Yan, Xinrui Ren, Bo Zhang

Institution: Jiangsu University

Language: English

Topic: Advanced oxidation water treatment

Subfield: Water Science and Technology

Field: Environmental Science

Domain: Physical Sciences

SDGs: Clean water and sanitation, Responsible consumption and production

Open Access status: gold

Estimated APC paid: $3,137