Work

Extraordinary kinetic inertness of lanthanide( iii ) complexes of pyridine-rigidified 18-membered hexaazamacrocycles with four acetate pendant arms

Year: 2025

Type: article

Abstract: With Ln 3+ ions, the H 4 pyta forms isomeric complexes having CN 10 or 9, and the ten-coordinated complexes are up to 10 4 times more kinetically inert than the Ln( iii )–H 4 dota complexes.

Source: Chemical Science

DOI: 10.1039/d5sc01893e

Authors: Jan Faltejsek, Peter Urbanovský, Vojtěch Kubíček, Jana Havlíčková, Ivana Císařová, Jan Kotek, Petr Hermann

Institution: Charles University

Language: English

Topic: Lanthanide and Transition Metal Complexes

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: Univerzita Karlova v Praze, Grantová Agentura, Univerzita Karlova, Grantová Agentura České Republiky

Awards: G3602869331, Large polyaza macrocycles with coordinating pendant arms as ligands for large metal ions

OpenAlex ID: W4410889586

FWCI: 1.898

Cites: 34

Cited by: 9

Related to: 10