Work

Examining the nucleation mechanism of calcium oxalate nanoparticles, with and without surfactants, and assessing the influence of surfactants on nanoparticle size

Year: 2025

Type: article

Abstract: This article describes the reactive crystallization method used for nanoparticle production. It emphasizes the significance of determining and controlling the nucleation mechanism by measuring induction time and solution supersaturation. Classical nucleation theory (CNT) was applied to identify the nucleation mechanism. Two surfactants, CTAB (Cetyltrimethylammonium bromide) and SDS (Sodium dodecyl sulfate), were utilized to prevent nanoparticle agglomeration. The presence of CTAB decreased the induction time (14 seconds), whereas SDS increased it (41 seconds). Calcium oxalate nanoparticles formed through a homogeneous primary nucleation mechanism, unaffected by the type of surfactant. However, SDS resulted in smaller particles (under 100 nm) with a more uniform size distribution compared to CTAB.

Source: Results in Chemistry

DOI: 10.1016/j.rechem.2025.102435

Authors: Milad Hejazifar, Mehrdad Manteghian, Seyed Pezhman Shirmardi

Institutions: Tarbiat Modares University, Nuclear Science and Technology Research Institute

Language: English

Topic: Crystallization and Solubility Studies

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,870

Funder: Tarbiat Modares University