Work

Self-supplying coreactant radical and structural distortion induced by carbonate ligand in metal–organic framework for anomalous deep-red Self-electrochemiluminescence

Year: 2025

Type: article

Abstract: The potential of CO 3 2− ligand in self-electrochemiluminescence (self-ECL) was exploited. The CO 3 2− unit can generate a coreactant radical and cause distortion of the structure to trigger an unusual electric-dipole transfer transition in 5 D 0 – 7 F 4 .

Source: Chemical Science

DOI: 10.1039/d5sc02359a

Authors: Lu Zhao, Zhenjie Xu, Xianzhen Song, Caifeng Ding, Huangxian Ju

Institutions: Qingdao University of Science and Technology, State Key Laboratory of Analytical Chemistry for Life Science, Nanjing University

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Natural Science Foundation of Shandong Province, Taishan Scholar Foundation of Shandong Province

Awards: G1527593979, G3134464807, G5939345601, G6496242538