Synthesis, Structure, and 199 Hg Chemical Shifts of Mercury 1,5,9‐trimesityldipyrromethene ( Mes DPM) Complexes
Year: 2025
Type: article
Abstract: In this work, we describe the easy synthesis of mercury complexes with the 1,5,9‐trimesityldipyrromethene ( Mes DPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single‐crystal X‐ray diffraction analysis (SC‐XRD) experiments. In addition, the 199 Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.
Source: Chemistry - A European Journal
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
Funders: National Science Foundation, Deutscher Akademischer Austauschdienst, Deutsche Forschungsgemeinschaft, Fundação de Amparo à Pesquisa do Estado de São Paulo, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Ministério da Ciência, Tecnologia e Inovação, Conselho Nacional de Desenvolvimento Científico e Tecnológico, University of California, Santa Barbara, University at Buffalo, Division of Chemistry
Awards: Exploring Response Properties of Molecules and Extended Systems Using Theoretical Methods, G295657101, G3862245860, G3941215402, Harnessing the Reactivity of Sulfur: From Novel S-Atom Transfer Reagents to Sulfide-Protected Nanoclusters, Solvent Effect on NMR Parameters of Tl(III) and Pt(IV) Complexes by ab initio Molecular Dynamics and Relativistic Calculations, G6070492641, Exploring Response Properties of Molecules and Extended Systems Using Theoretical Methods, G7504169866, G7672367281, G93419608
OpenAlex ID: W4411340416