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Asymmetric intramolecular reductive coupling of bisimines templated by chiral diborons

Year: 2025

Type: article

Abstract: An asymmetric intramolecular reductive coupling of bisimines is accomplished, providing the unprecedented chiral dihydrophenanthrene-9,10- cis -diamines in high yields and ees. An uncommon twisted-boat pathway is featured in this protocol.

Source: Chemical Science

DOI: 10.1039/d5sc03633j

Authors: Tian Chen, Hao-Yang Wang, Ronghua Xu, Guangqing Xu, He Yang, Jiangtao Sun, Lung Wa Chung, Wenjun Tang

Institutions: Changzhou University, Southern University of Science and Technology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Science and Technology Commission of Shanghai Municipality, Youth Innovation Promotion Association of the Chinese Academy of Sciences, Southern University of Science and Technology, Guangdong Provincial Key Laboratory Of Catalysis, National Key Research and Development Program of China, Youth Innovation Promotion Association

Awards: G128716482, G3526456555, G3711659720, G4497227990, G6737186453, G6965922775, G741154071, G7802288526

OpenAlex ID: W4411380581

FWCI: 0.894

Cites: 57

Cited by: 3

Related to: 10