Work

Design of Cobalt-Free Ni-Rich Cathodes for High-Performance Sodium-Ion Batteries Using Electrochemical Li+/Na+ Exchange

Year: 2025

Type: article

Abstract: Sodium-ion batteries are renowned for their abundant reserves, cost-efficiency, safety, and eco-friendliness and are prime candidates for large-scale energy storage applications. The development of cathode materials plays a crucial role in shaping both the commercialization path and the ultimate performance capabilities of SIBs. To overcome the intricate synthesis challenges associated with pure-phase sodium-ion cathode materials, this study introduces an innovative and streamlined electrochemical Li+/Na+ exchange process, successfully fabricating a high-capacity Ni-rich cathode material. This cathode material boasts a remarkable reversible capacity of 180 mAh g−1 at 0.1 C and retains a high-rate capacity of 115 mAh g−1 even at 5 C. Additionally, it exhibits exceptional cycling stability, retaining about 85% of its capacity at 1 C after 50 cycles and still maintaining a capacity greater than 60% after 100 cycles. The Na-NMA85 full cell preserves a discharge capacity of 110 mAh g−1 after 100 cycles, with a capacity retention rate of 80%. This research underscores innovative strategies for designing ion-intercalation-based cathode materials that enhance battery performance, providing fresh perspectives for advancing high-performance battery technologies.

Source: Energies

DOI: 10.3390/en18123205

Authors: Yao Lv, Liqiu Shi, Jianfeng Yu, Shifei Huang

Institutions: Zhejiang University of Water Resource and Electric Power, Yangzhou University

Language: English

Topic: Advancements in Battery Materials

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $3,137