Work

Structural control of dynamic covalent cages: kinetic vs. thermodynamic assembly and PFAS removal from water

Year: 2025

Type: article

Abstract: Selective formation of low-symmetry Tri22Tri 2 via dynamic covalent chemistry was achieved. Solvent choice enabled kinetic or thermodynamic control, directing assembly towards Tri22Tri 2 or high-symmetry Tri 4 Tri 4 cages.

Source: Chemical Science

DOI: 10.1039/d5sc02247a

Authors: Tobias Pausch, Pablo Martínez Mestre, Fabiola Zapata, Andreas Mix, Bernd M. Schmidt

Institutions: Heinrich Heine University Düsseldorf, Universidad de Murcia, Bielefeld University

Language: English

Topic: Supramolecular Chemistry and Complexes

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Fundación Séneca, Deutsche Forschungsgemeinschaft, Evangelisches Studienwerk Villigst, Universidad de Murcia, Ministerio de Ciencia e Innovación

Awards: G1141136363, G5805502524, G725668855

OpenAlex ID: W4411420118

FWCI: 2.335

Cites: 83

Cited by: 8

Related to: 10