Work

Oxidative addition of Si–H bonds to metal-decorated Zintl clusters [Hyp 3 Ge 9 Ir(CO)PR 3 ] (R = Ph, p tolyl, Me)

Year: 2025

Type: article

Abstract: }Ph, and Ph/H) to the Ir atom is investigated. The addition reaction is directly monitored by NMR spectroscopy. Additionally, LIFDI/MS, IR spectroscopy, and single crystal structure determination of the addition products confirm the reaction. X-ray photoelectron spectroscopy (XPS) reveals that the transition metal atom and the Ge atoms of the supporting cluster have a low oxidation state.

Source: Dalton Transactions

DOI: 10.1039/d5dt01147g

Authors: Nicole S. Willeit, Tim Kratky, Viktor Hlukhyy, Sebastian Günther, Thomas F. Fässler

Institution: Technical University of Munich

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funder: Wacker

OpenAlex ID: W4411433457

FWCI: 0.217

Cites: 53

Cited by: 1

Related to: 10