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Stereocontrolled four-carbon homologation of vicinally functionalized allylic pyrrolidines to highly customized azonines bearing remote benzylic stereocenters

Year: 2025

Type: article

Abstract: Vicinally functionalized (bis) allylic pyrrolidines have been skeletally remodelled via HFIP-promoted aza-Cope rearrangement to highly decorated nine-membered azaheterocycles (azonines), which harbor benzylic stereocenters.

Source: RSC Advances

DOI: 10.1039/d5ra03502c

Authors: Timothy K. Beng, Ailan Johnsen, Alan Gitonga, Jasleen Kaur

Institution: Central Washington University

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,042

Funders: School of Graduate Studies, Utah State University, Central Washington University, Office of Undergraduate Research, College of Arts and Sciences, Washington University in St. Louis

OpenAlex ID: W4411453174

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Cites: 62

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Related to: 10