Year: 2025
Type: article
Abstract: We investigate suspensions of non-Brownian, millimetric monodisperse spherical particles floating at quasi-two-dimensional fluid interfaces, from dilute to dense concentrations. Building upon the phase diagram in the capillary number ( $Ca$ ) and areal fraction ( $\phi$ ) constructed by Shin & Coletti (2024 J. Fluid Mech.984, R7), we analyse the dynamics of both aggregation and dispersion. In the capillary-driven clustering regime ( $Ca \lt 1$ ), strong inter-particle bonds yield large, fractal-like clusters that grow by hit-and-stick collisions. In the drag-driven break-up regime ( $Ca \gt 1$ , $\phi \lt 0.4$ ), turbulent fluctuations overcome capillarity and result in particles moving similarly to passive tracers and forming clusters by random adjacency. In the lubrication-driven clustering regime ( $Ca \gt 1$ , $\phi \gt 0.4$ ), the close inter-particle proximity amplifies lubrication forces and results in large, crystal-like clusters. Above a threshold concentration that depends on $Ca$ , self-similar percolating clusters span the entire domain. The particle transport exhibits a classic ballistic-to-diffusive transition, with the long-time diffusivity hindered by the reduced fluctuating energy at high concentrations. Nearby particles separate at initially slow rates due to strong capillary attraction, and then follow a super-diffusive dispersion regime. In dense suspensions, the process is characterised by the time scale associated with inter-particle collisions and by the energy dissipation rate defined by the lubrication force between adjacent particles. Our results provide a framework for predicting particle aggregation in interfacial suspensions such as froth flotation and pollutant dispersion, and may inform the design of advanced materials through controlled colloidal self-assembly.
Source: Journal of Fluid Mechanics
Institutions: ETH Zurich, Otto-von-Guericke-Universität Magdeburg
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,550
OpenAlex ID: W4411501023