Work

New single-crystal X-ray diffraction and Raman spectroscopic data of natural bismoclite BiOCl

Year: 2025

Type: article

Abstract: The structure of bismoclite BiOCl from the Jean Baptiste mine, Lavrion area, Greece, was characterised by single-crystal X-ray diffraction. The mineral is tetragonal, space group P 4/ nmm with unit-cell parameters a = 3.887 (2), c = 7.357 (5) Å, Z = 2, V = 111.16 (14) Å 3 ( R 1 = 0.0134 and wR 2 = 0.0363). Bismoclite is isostructural with the mineral matlockite PbFCl. Chemical analyses showed in some cases partial substitution of Bi by Ca and traces of Fe incorporated. A Raman spectrum of bismoclite reveals the most intense Raman band at 144 cm –1 and additional bands of lower intensity at 198 and 396 cm –1 .

Source: Mitteilungen der Österreichischen Geologischen Gesellschaft/Austrian journal of earth sciences

DOI: 10.17738/ajes.2025.0007

Authors: Irene Liebhart, Branko Rieck, Manuela Zeug, Gerald Giester

Institution: University of Vienna

Language: English

Topic: Mineralogy and Gemology Studies

Subfield: Geochemistry and Petrology

Field: Earth and Planetary Sciences

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4411523690

FWCI: 0.991

Cites: 37

Cited by: 2

Related to: 10