Work

Hydrogen-bond mediated electrocatalytic nitrate reduction to ammonia over metal–organic frameworks with industrial current density

Year: 2025

Type: article

Abstract: A hydrogen bonding strategy is proposed to stabilize *NO 2 intermediates to improve the activity of the NO 3 − reduction reaction. The optimal DiMe-Cu 3 -MOF shows high NH 3 faradaic efficiency (95%) and large partial current density of −950.6 mA cm −2 .

Source: Chemical Science

DOI: 10.1039/d5sc02208h

Authors: Xiao-Xue Fu, Hui Guo, Duan-Hui Si, Hong-Jing Zhu, Yi-Ying Lan, Yuan-Biao Huang, Rong Cao

Institutions: Chinese Academy of Sciences, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, State Key Laboratory of Structural Chemistry, Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China

Language: English

Topic: Ammonia Synthesis and Nitrogen Reduction

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, National Key Research and Development Program of China, Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China

Awards: G1402713694, G1956296004, G2556797165, G2661244104, G3576258390, G5219652432, G5469566844, 卟啉基阳离子型共价有机框架串联催化二氧化碳与烯烃反应制环状碳酸酯, G7000313635, G8564877110

OpenAlex ID: W4411580374

FWCI: 5.339

Cites: 48

Cited by: 39

Related to: 10