Year: 2025
Type: article
Abstract: , forming bisphosphine adducts as regioisomeric mixtures with reduced P-C bond stability. Spectroscopic, crystallographic, and computational analyses reveal the presence of σ-type dative P-C bonds and significant charge redistribution within the fullerene cage. Furthermore, functionalizations of the phosphonium fullerides with electrophiles yield ionic derivatives, highlighting their reactivity and potential for further modification.
Source: Chemical Science
DOI: 10.1039/d5sc00367a
Authors: Maike B. Röthel, Jonas H. Franzen, Daniel Leitner, Thomas S. Hofer, Michael Seidl, Fabian Dielmann
Institution: Universität Innsbruck
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
Award: G3291570854
OpenAlex ID: W4411698553