Dielectric stabilization controls excited-state proton transfer and ion pair dynamics in organic solvents
Year: 2025
Type: article
Abstract: < 10), the population is trapped as solvent-separated ion pairs and full dissociation becomes operative only at intermediate polarity. Ground-state recombination of the intermediate ion pair species is fast and thus a significant population of fully dissociated ground-state ions is produced only above intermediate polarities.
Source: Chemical Science
DOI: 10.1039/d5sc03404c
Authors: Amar Raj, Pragya Verma, Andrei Beliaev, Pasi Myllyperkiö, Tatu Kumpulainen
Institutions: University of Jyväskylä, University of Geneva
Language: English
Subfield: Physical and Theoretical Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
Funder: Jyväskylän Yliopisto
OpenAlex ID: W4411809700