Work

Synthesis and Application of FeMg-Modified Hydrochar for Efficient Removal of Lead Ions from Aqueous Solution

Year: 2025

Type: article

Abstract: This study explores the utilization of waste grape pomace-derived hydrochar as an efficient adsorbent for lead (Pb2+) removal from aqueous solutions. Hydrochar was produced via hydrothermal carbonization (HTC) at 220 °C, followed by doping with magnesium and iron salts, and subsequent pyrolysis at 300 °C to obtain Fe/Mg-pyro-hydrochar (FeMg-PHC). The material’s structural and morphological changes after Pb2+ adsorption were examined using FTIR. FTIR revealed chemisorption and ion exchange as key mechanisms, shown by decreased hydroxyl, carbonyl, and metal–oxygen peaks after Pb2+ adsorption. Adsorption tests under varying pH, contact time, and initial Pb2+ concentrations revealed optimal removal at pH 5. Kinetic modeling indicated that the process follows a pseudo-second-order model, suggesting chemisorption as the dominant mechanism. Isotherm analysis showed that the Sips model best describes the equilibrium, with a maximum theoretical adsorption capacity of 157.24 mg/g. Overall, the simple two-step synthesis—HTC followed by pyrolysis—combined with metal doping yields a highly effective and sustainable adsorbent for Pb2+ ion removal from wastewater.

Source: Processes

DOI: 10.3390/pr13072060