Work

The Lewis basicity of amines on the Legault iodonium Lewis acidity scale

Year: 2025

Type: article

Abstract: Diaryliodonium-amine complexes are proposed as key intermediates in C–N coupling reactions. The Lewis basicity of synthetically relevant amines are quantified on the Legault iodonium Lewis acidity scale.

Source: Chemical Communications

DOI: 10.1039/d5cc01711d

Authors: Soocheta Jha, Souradeep Basu, Madison Bob, David R. Stuart

Institution: Portland State University

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funder: National Science Foundation

Awards: Probing the Solution-Phase Dynamics of l3-Iodanes and Relation to Reactivity, G8126199308, CAS: Interrogating the Intersection of Structure, Bonding, and Reactivity of Hypervalent Halogens

OpenAlex ID: W4411911733

FWCI: 0.596

Cites: 17

Cited by: 2

Related to: 10