Work

Facile N–C bond cleavage and arene reduction by a transient uranium( ii ) complex

Year: 2025

Type: article

Abstract: -U(iii)). These results indicate that polydentate amine-phenolate ligands can be used to access highly reactive U(ii) intermediates and that provides evidence that U(ii) species are involved in the formation of inverse sandwich complexes.

Source: Chemical Science

DOI: 10.1039/d5sc03694a

Authors: R. A. Keerthi Shivaraam, Leonor Maria, Thayalan Rajeshkumar, Rosario Scopelliti, Ivica Živković, Andrzej Sienkiewicz, Laurent Maron, Marinella Mazzanti

Institutions: École Polytechnique Fédérale de Lausanne, University of Lisbon, Instituto Superior Técnico, Centro de Química Estrutural, Institut National des Sciences Appliquées de Toulouse, Laboratoire de Physique et Chimie des Nano-Objets, Laboratoire Anthropologie, Archéologie, Biologie, Equipe de recherche paramédicale sur le handicap neuromoteur

Language: English

Topic: Radioactive element chemistry and processing

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, École Polytechnique Fédérale de Lausanne, Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, Institut Universitaire de France, Centro de Química Estrutural, Fundação para a Ciência e a Tecnologia

Awards: G1570005492, Design of f-f and f-d polyheterometallic architectures for cooperative small molecule activation, G2578531282, Centro de Química Estrutural, Instituto de Ciências Moleculares, G6508582484, G681548056, DESIGN OF MULTIMETALLIC COMPLEXES OF F-ELEMENTS IN UNUSUAL OXIDATION STATES: ACTIVATION AND FUNCTIONALIZATION OF DINITROGEN AND MAGNETIC PROPERTIES

OpenAlex ID: W4411922926

FWCI: 0.434

Cites: 73

Cited by: 2

Related to: 10