Work

Pd@POPs-catalyzed carbonylative transformations of aryl bromides: Efficient synthesis of esters, amides, and topramezone

Year: 2025

Type: article

Abstract: In this study, we thoroughly investigated the performance of Pd@POPs in the heterogeneous catalytic carbonylation of aryl bromides. A variety of phenols and amines could be efficiently converted into the corresponding ester and amide products with good to excellent yields. This catalytic system was successfully applied in the synthesis of the agrochemical molecule topramezone, achieving an outstanding yield.

Source: Green Synthesis and Catalysis

DOI: 10.1016/j.gresc.2025.06.012

Authors: Ren-Rui Xu, Xingju Li, Li Yan, Yunjie Ding, Xiangen Song, Xiao-Feng Wu

Institutions: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy

Language: English

Topic: Catalytic Cross-Coupling Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, China Postdoctoral Science Foundation, National Key Research and Development Program of China

Awards: G3457430526, G4665371913, G4833463889