A Novel Ti 12 ‐Based Metal‐Organic Framework for Photocatalytic Hydrogen Evolution (Adv. Energy Mater. 26/2025)
Year: 2025
Type: article
Abstract: Photocatalytic Hydrogen Evolution MIP-209(Ti) is a new microporous metal-organic framework (MOF) built up from Ti12O15 clusters and substituted terephthalate linkers, enabling isoreticular chemistry and clusters tunability for photocatalytic applications. Cr3+ doping (≤5 at%) on Ti-oxoclusters enhances water stability and markedly boosts hydrogen production from water under simulated solar light irradiation. Significant photocatalytic activity is achieved without noble metals, paving the way for tunable Ti-MOF-based photocatalysts. More in article number 2500211, Georges Mouchaham, Christian Serre, and co-workers.
Source: Advanced Energy Materials
Authors: Bingbing Chen, Asma Mansouri, Celia M. Rueda‐Navarro, Iurii Dovgaliuk, Philippe Boullay, Arianna Melillo, Juan José Ramírez‐Hernández, Beibei Xiao, Dong Fan, Lokuge Aravindani Fernando, Gilles Patriarche, Ieuan Cornu, Pierre Florian, Guillaume Maurin, Sergio Navalón, Hermenegildo Garcia, Georges Mouchaham, Christian Serre
Institutions: Centre National de la Recherche Scientifique, Université Paris Sciences et Lettres, École Normale Supérieure - PSL, Institut des Matériaux Poreux de Paris, ESPCI Paris, Universitat Politècnica de València, École Nationale Supérieure d'Ingénieurs de Caen, Laboratoire de Cristallographie et Sciences des Matériaux, Université de Caen Normandie, École Nationale Supérieure de Chimie de Montpellier, Université de Montpellier, Jiangsu University of Science and Technology, Institut Charles Gerhardt Montpellier, Centre de Nanosciences et de Nanotechnologies, Université d'Orléans, Conditions Extrêmes et Matériaux Haute Température et Irradiation
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4412111443