Work

Steric pressure in heteropentacenes modulates the photophysical properties – a molecular design strategy for functional materials

Year: 2025

Type: article

Abstract: -methyl groups influences the vertical electronic transitions, tuning the emission colors from red over yellow to green and inverting the preferred state of luminescence from solution to solely the solid-state or even both. An in-depth analysis was performed using X-ray diffractometric structure elucidation, packing analysis and density functional theory calculations to correlate the photophysical properties with the steric pressure induced by the methyl groups. Additionally, the application scope of these new materials was investigated. Mesoporous silica nanoparticles loaded with the three new luminophores were prepared and employed as additives for 3D printing using digital light processing. Ultimately, these stimuli-responsive molecules performed as optical sensors of microenvironmental temperature and phase transition changes in liquid crystals.

Source: Chemical Science

DOI: 10.1039/d5sc03028e