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Photoredox-catalyzed arylation of isonitriles by diaryliodonium salts towards benzamides

Year: 2025
Type: article
Abstract: The arylation of isonitriles by diaryliodonium salts under photoredox conditions has been proposed for the first time. The suggested procedure allows preparing a broad range of benzamides using both symmetric and unsymmetric diaryliodonium salts under mild conditions. A plausible mechanism for the reaction and the selectivity of aryl transfer (in case of unsymmetrical iodonium salts) were studied.
DOI: 10.3762/bjoc.21.110
Authors: Nadezhda M Metalnikova, Nikita S Antonkin, Tuan K Nguyen, Natalia S Soldatova, Alexander V Nyuchev, Mikhail A Kinzhalov, Pavel S Postnikov
Language: English
Field: Chemistry
Open Access status: diamond
OpenAlex ID: W4412514591
FWCI:
Cites: 43
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Related to: 10