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Zinc substituted carbenes: synthesis, structure, and ambiphilic reactivity

Year: 2025

Type: article

Abstract: Zinc-substituted singlet carbenes featuring near-linear geometries are synthesized. Reactivity studies demonstrate ambiphilic behavior and provide a direct route to heterobimetallic μ-carbyne complexes.

Source: Chemical Science

DOI: 10.1039/d5sc03342j

Authors: Shengjie Jiang, Ganping Wang, Yanping Cai, Laurent Maron, Xin Xu

Institutions: Soochow University, Centre National de la Recherche Scientifique, Université Toulouse III - Paul Sabatier, Institut National des Sciences Appliquées de Toulouse, Laboratoire de Physique et Chimie des Nano-Objets

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, China Scholarship Council, Institut Universitaire de France

Awards: G1994613851, G7015076382

OpenAlex ID: W4412581207

FWCI: 0.434

Cites: 34

Cited by: 2

Related to: 10