Work

Room-temperature FeSi2-doped Cu2Se thermoelectric films with enhanced figure of merit

Year: 2025
Type: article
Abstract: Thermoelectric (TE) materials offer a promising pathway toward achieving carbon neutrality by converting waste heat into electricity. The enhancement of their figure-of-merit (zT) depends on optimizing the composition of materials and nanostructures, reducing the thermal conductivity, and increasing the power factor. Cu 2 Se, a superionic material, achieves a zT of 0.4 at 300 K by facilitating Cu ion movement within its face-centered cubic lattice, effectively suppressing thermal conductivity. Herein, we present a novel TE material developed by doping Cu x Se crystals of different compositions with FeSi 2 . We report a remarkable zT of 0.69 at 298 K for Cu 2 Se-based materials and reveal the presence of the CuO and Cu 2 O tiny crystals on the material surface, uniform dispersion of Si within the film, and formation of distinctive amorphous FeO. Our strategy holds great potential for notably advancing waste heat recovery in sustainable TE materials.
Language: English
Open Access status: gold
Estimated APC paid: $2,690
OpenAlex ID: W4412656458
FWCI: 1.272
Cites: 41
Cited by: 6
Related to: 10