Work

Synthesis of Poly(5-norbornene-2,3-dicarboxylic Anhydride) by ROMP in the Presence of the Second-Generation Grubbs Catalyst and 1-Hexene in DMF

Year: 2025

Type: article

Abstract: The results of investigations on the ring-opening metathesis polymerization (ROMP) of 5-norbornene-2,3-dicarboxylic acid anhydride (NDA) under the action of the second-generation Grubbs catalyst in the presence of 1-hexene, acting as a chain transfer agent, in DMF in order to synthesize a soluble low-molecular-weight polymer containing reactive groups are presented. The effect of polymerization conditions on the molecular weight and thermal properties of the resulting metathesis polymers based on NDA was determined.

Source: INEOS OPEN

DOI: 10.32931/io2514a

Authors: I. V. Ignatyev, N. P. Bezrukov, V. Ya. Melekhina, A. A. Morontsev, S. V. Antonov, M. V. Bermeshev

Institutions: MIREA - Russian Technological University, Russian Academy of Sciences, A.V. Topchiev Institute of Petrochemical Synthesis

Language: English

Topic: Synthetic Organic Chemistry Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Russian Science Foundation, Russian Academy of Sciences

OpenAlex ID: W4412697838