Work

Destabilization of ammonia borane via dual confinement in a cobalt-based Prussian blue analogue

Year: 2025

Type: article

Abstract: The lacunar Co II [Co III (CN) 6 ] 2/3 □ 1/3 Prussian blue analogue confines ammonia borane (NH 3 BH 3 ) via a dual mechanism: with chemisorption onto coordinatively unsaturated Co 2+ sites and physisorption within the vacancies of the porous structure.

Source: Sustainable Energy & Fuels

DOI: 10.1039/d5se00758e

Authors: Maëlle Cahu, Carlos A. Castilla-Martinez, Fabrice Salles, Jérôme Long, Umit B. Demirci

Institutions: École Nationale Supérieure de Chimie de Montpellier, Centre National de la Recherche Scientifique, Institut Charles Gerhardt Montpellier, Institut Européen des Membranes, Institut Universitaire de France

Language: English

Topic: Hydrogen Storage and Materials

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funders: Agence Nationale de la Recherche, Institut Universitaire de France, Région Occitanie Pyrénées-Méditerranée

Awards: G1190173965, SOLid storage of HYDdrogen: new strategies, new materials