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The side-arm-effect controlled stereodivergent polymerization of 1-butene

Year: 2025

Type: article

Abstract: Tridentate titanium complexes with different side-arm donors were employed for the efficient (activity of up to 3.41 × 10 6 g mol −1 h −1 ) production of poly(1-butene) with multiple types of isotacticity (ranging from atactic to 91% mmmm ).

Source: Polymer Chemistry

DOI: 10.1039/d5py00583c

Authors: Guangyu Zhu, Liang Wang, Wenjie Tao, Hongbin Hou, Guangqiang Xu, Bo Wang, Qinggang Wang

Institutions: Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, University of Chinese Academy of Sciences

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: National Natural Science Foundation of China, Natural Science Foundation of Shandong Province, Taishan Scholar Project of Shandong Province

Awards: G3000659218, G3885247432, G4700327624, G6672478523

OpenAlex ID: W4412815162

FWCI:

Cites: 92

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Related to: 10