Work

Tuning flexibility in metal–organic frameworks via linker per-fluorination: revisiting the adsorption-induced breathing of MIL-53(Al)

Year: 2025

Type: article

Abstract: In situ characterisation of the multi-step adsorption-induced breathing behaviour of F 4 -MIL-53(Al) unveiled the impact of fluorination on framework flexibility and adsorption properties, offering new insights into dynamic porosity in MOFs.

Source: Journal of Materials Chemistry A

DOI: 10.1039/d5ta04373e

Authors: Virginia Guiotto, Maria Sole Notari, Jacopo Perego, Diletta Morelli Venturi, Francesca Nardelli, Alberto Ricchebuono, Silvia Bordiga, Susana Garcia, Marco Taddei, Matteo Signorile, Angiolina Comotti, Lucia Calucci, Ferdinando Costantino, Valentina Crocellà

Institutions: National Interuniversity Consortium of Materials Science and Technology, University of Turin, University of Perugia, University of Milano-Bicocca, Christian-Albrechts-Universität zu Kiel, University of Pisa, Institute for the Chemistry of OrganoMetallic Compounds, National Research Council, IFP Énergies nouvelles, Heriot-Watt University

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Dipartimenti di Eccellenza, European Commission, Deutsche Forschungsgemeinschaft, Ministero dell'Università e della Ricerca, HORIZON EUROPE Framework Programme, HORIZON EUROPE European Innovation Council, European Innovation Council and Small and Medium-sized Enterprises Executive Agency

Awards: G1303340219, G186868166, Double-Active Membranes for a sustainable CO2 cycle, G3191337241, (Per-)fluorinateD metal-Organic frameworks-based Mixed matrIx membraNes for large-scale carbon diOxide separation. (doMino), G350782048, G5386476940, G640733617, G683883107, G7263791912

OpenAlex ID: W4412978591

FWCI: 2.768

Cites: 59

Cited by: 13

Related to: 10