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Rhenacarborane [1,1-(CO)2-1,1-I2-isonido-1,2,4-ReC2B8H10]–. Synthesis, Properties, and Molecular Structure

Year: 2025

Type: article

Abstract: The reaction of a rhenium carborane complex [1,1,1-(CO)3-isonido-1,2,4-ReC2B8H10]– tmndH+ (1) with an equimolar amount of I2 in CH2Cl2 at room temperature for 1 h leads to the formation of complex [1,1-(CO)2-1,1-I2-isonido-1,2,4-ReC2B8H10]– tmndH+ (2). The structure of complex 2 was confirmed by the data of NMR, IR, and UV-Vis spectroscopy, elemental analysis, and X-ray diffraction. In addition, complexes (1) and (2) were studied by cyclic voltammetry.

Source: INEOS OPEN

DOI: 10.32931/io2519a

Authors: E. V. Balagurova, F. M. Dolgushin, E. G. Kononova, A. A. Kissel, S. M. Peregudova

Language: English

Topic: Boron Compounds in Chemistry

Subfield: Radiology, Nuclear Medicine and Imaging

Field: Medicine

Domain: Health Sciences

Open Access status: hybrid

OpenAlex ID: W4413022411

FWCI:

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