Synthesis, structure and slow magnetic relaxation of lanthanoid coordination polymers based on ethynyl-bridged picolinate ligands
Year: 2025
Type: article
Abstract: space group and form anionic layers with rhomboidal voids. AC magnetic susceptibility measurements show that compounds based on Kramers ions, such as the Gd (2), Dy (4) and Er (6) derivatives, present slow relaxation of magnetization (SRM) under an applied DC magnetic field. On the other hand, Tb (3) and Ho (5) compounds, based on non-Kramers ions, lack SRM properties. Compound 2 is one of the few reported Gd(III) compounds showing slow relaxation behaviour.
Source: Dalton Transactions
DOI: 10.1039/d5dt01330e
Institution: Universitat de València
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Awards: G1168373365, G1175115578, G120905174, G123897006, G1272927172, G1422035950, G1530851820, G1549819418, G1622782223, G210041235, G2262748287, G2513399825, G2586187451, G2601397997, G300979063, G3193775030, G3274226867, G34346518, G3480869486, G348919436, G357246561, G3681454997, G4042783231, G410571670, G425668148, G451917667, G5080475149, G5195188938, G529962013, G531036588, G5539308778, G5967599077, G6033532046, G7084143925, G7612190007, G792975244, G929308097
OpenAlex ID: W4413035833