Work

Annulative endoperoxidation of tetronates

Year: 2025

Type: article

Abstract: A novel, annulative endoperoxidation of tetronate derivatives bearing unsaturated side chains is presented. The reaction requires a simple setup and proceeds under mild conditions to generate tricyclic endoperoxides in modest diastereoselectivities and useful yields. A free-radical mechanism is proposed.

Source: Organic & Biomolecular Chemistry

DOI: 10.1039/d5ob00663e

Authors: Najmeh Rahimi, Saba Sehrish, Samuel K. Akompong, Bayler G. Barnes, Cory J. Windorff, Marat R. Talipov, Rodolfo Tello-Aburto

Institution: New Mexico State University

Language: English

Topic: Organic Chemistry Synthesis Methods

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: New Mexico State University, National Institutes of Health, National Institute of General Medical Sciences

Awards: G1799857530, G620453595, G9000015656

OpenAlex ID: W4413110048

FWCI:

Cites: 52

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Related to: 10