Work

Accessing phosphonioacetylide chemistry: isolable alkali metal precursors for rod-shaped carbon donor complexes

Year: 2025

Type: article

Abstract: The high reactivity of a sterically accessible phosphonioacetylide was tamed via alkali metal coordination. The resulting complexes are precursors for introducing the rod-shaped, strongly electron-donating ligand into transition metal complexes.

Source: Inorganic Chemistry Frontiers

DOI: 10.1039/d5qi01286d

Authors: Franka Brylak, Pawel Löwe, Klaus Wurst, Stephan Hohloch, Fabian Dielmann

Institutions: Universität Innsbruck, University of Münster

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: Deutsche Forschungsgemeinschaft, Technische Universität München, Universität Innsbruck

Award: G55733167