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Multi-electron redox reactivity of a thorium( ii ) hydride synthon

Year: 2025

Type: article

Abstract: The double-sandwich bimetallic hydride complex [(Cp Ar5 )Th(μ-H)] 2 , regarded as a thorium( ii ) hydride synthon, not only serves as the six-electron transfer reagent, but also promotes the four-electron reductive coupling and Th–H addition reactions.

Source: Chemical Science

DOI: 10.1039/d5sc03403e

Authors: Xianghui Shi, Guorui Qin, Peng Deng, Iker Del Rosal, Laurent Maron, Jianhua Cheng

Institutions: Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, University of Science and Technology of China, Centre National de la Recherche Scientifique, Université Toulouse III - Paul Sabatier, Institut National des Sciences Appliquées de Toulouse, Laboratoire de Physique et Chimie des Nano-Objets, Université de Toulouse

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Chinese Academy of Sciences, Institut Universitaire de France

Award: G1719288083

OpenAlex ID: W4413164387

FWCI: 0.298

Cites: 66

Cited by: 1

Related to: 10