Work

Development of low-emission photocatalytic cement composites with co-ground TiO2-fly ash and TiO2-calcium carbonate systems

Year: 2025

Type: article

Abstract: This study presents an innovative method for producing low-emission cement composites with photocatalytic properties by partially replacing Portland cement with fly ash, ground granulated blast furnace slag, and calcium carbonate. Novel ground systems combining fly ash-TiO2 or calcium carbonate-TiO2 were synthesized via high-energy ball milling to enhance dispersion and minimize TiO2 agglomeration. The modified composites exhibited improved hydration kinetics, including reduced setting times and up to 50% lower cumulative hydration heat. Mechanical tests confirmed comparable or superior compressive and flexural strengths as compared with the reference materials. All TiO2-containing composites showed UV-induced photocatalytic activity, with anatase-based systems yielding the best results. Carbon footprint analysis confirmed the environmental benefits, particularly in reducing CO2 emissions. These findingssupport the development of multifunctional, sustainable cementitious materials for eco-efficient construction.

Source: Bulletin of the Polish Academy of Sciences Technical Sciences

DOI: 10.24425/bpasts.2025.155898

Authors: Agnieszka Ślosarczyk, Izabela Klapiszewska, Patryk Jędrzejak, Marta Thomas, Łukasz Klapiszewski

Institution: Poznań University of Technology

Language: English

Topic: Concrete and Cement Materials Research

Subfield: Civil and Structural Engineering

Field: Engineering

Domain: Physical Sciences

SDGs: Responsible consumption and production, Industry, innovation and infrastructure, Climate action

Open Access status: gold

Estimated APC paid: $283