Work

Iron‐Catalyzed Carbonylation Reactions with Carbon Monoxide

Year: 2025

Type: article

Abstract: The utilization of carbon monoxide (CO) as an inexpensive and indispensable C 1 feedstock for the efficient construction of diverse carbonylated compounds has been a subject of numerous studies for decades. Nowadays, transition metal‐catalyzed carbonylation represents a pivotal synthetic approach for the generation of carbonyl‐containing molecules. Among the known catalysts for these transformations, non ‐noble metal‐based systems have garnered increasing interest in recent years due to their substantial advantages, including wide availability, low cost, and low toxicity. In this review, we have summarized and discussed original and recent developments in iron‐catalyzed carbonylative transformations, wherein CO is utilized as the C 1 feedstock.

Source: Angewandte Chemie

DOI: 10.1002/ange.202512346

Authors: Kangkang Sun, Guo‐Ping Lu, Wei Han, Matthias Beller

Institutions: Nanjing Normal University, Leibniz Institute for Catalysis, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Nanjing University of Science and Technology

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $5,790

Funder: Jiangsu Provincial Department of Education