Work

Multifunctional role of Thiourea in engineering electrodeposited NiFe catalysts for efficient and durable oxygen evolution reaction

Year: 2025

Type: article

Abstract: ABSTRACT Electrodeposition is a cost-effective method to fabricate water splitting catalyst, but acheving uniform nanostructure and durable electrodeposits remains challenging. In this study, Ni-Fe oxyhydroxide catalyst were electrodeposited on Ni foam via two step metal dissolution electrodeposition (MDE) process in an ethlylene glycol water electrolyte with varying thiourea concentration (0∼0.15 M). The effect of thiourea on nucleation behavior, deposit morphology, composition, and oxygen evolution reaction (OER) performance was investigated using electrochemcial measurements and structural characterization. Thiourea profoundly affected the electrodeposition process. It shifted the nucleation mode from instanteous to progressive, resulting in more uniformly distributed nanostructures. As a leveling agent, thiourea inhibited excessive deposition in high field regins, and as complex agent, it selectively promoted Ni 2+ deposition, while suppressing Fe 2+ incorporation. The optimum thiourea concentration (0.05 M) produced a catalyst with an OER overpotential of 286 mV at 100 mA/cm 2 and a charge transfer resistance of 1.03 Ω, dramatically improved from 360mV at 100 mA/cm 2 and 21.6 Ω without thiourea. The addition of thiourea also increased the electrochemical active surface area and decrased the Tafel slope, indicating improved kinetics. In addition, the 0.05 M thiourea modified catalyst showed excellent durability, with no degradation in performance after 100 hrs at 100 mA/cm 2 . Thiourea is crtical additive that enables controlled nucleation, selective metal deposition dramatically improves the nanostructure, activity, and durability of Ni-Fe OER catalyst, offering promising strategy for high-efficient water electrolysis.

Source: Materials Today Sustainability

DOI: 10.1016/j.mtsust.2025.101202

Authors: Jaewon Lee, Yongseon Choi, Jiyoung Kim, Eunoak Park, Kiyoung Lee

Institution: Inha University

Language: English

Topic: Electrocatalysts for Energy Conversion

Subfield: Renewable Energy, Sustainability and the Environment

Field: Energy

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $2,530