Work

Magnetically Recoverable WO3/Fe3O4 Catalyst for the Selective Oxidation of Styrene to Benzaldehyde

Year: 2025
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide A magnetically recoverable catalyst, WO 3 /Fe 3 O 4, was successfully synthesized via a coprecipitation and calcination method and applied for the selective oxidation of styrene to benzaldehyde. Structural and surface characterizations (XRD, XRF, SEM, TEM, BET, VSM, and XPS) confirmed the successful integration of both components, mesoporosity, strong magnetic properties, and the presence of W 6+ and Fe 2+ /Fe 3+ species. Catalytic studies identified optimal conditions: 33 wt % WO 3 loading, 40 mg catalyst, 10 equiv H 2 O 2, 70 °C, and 24 h, resulting in a styrene conversion of 74.21% and a benzaldehyde selectivity of 82.10%. The catalyst exhibited excellent recyclability, maintaining high activity and selectivity across five cycles. These findings highlight WO 3 /Fe 3 O 4 as a promising, cost-effective, and easily recoverable catalyst for sustainable industrial oxidation processes.
Source: ACS Omega
Language: English
Subfield: Catalysis
Open Access status: gold
Estimated APC paid: $1,935
OpenAlex ID: W4413356010
FWCI: 0.278
Cites: 58
Cited by: 2
Related to: 10