Year: 2025
Type: article
Abstract: We report a direct in situ transmission electron microscopy (TEM) study of the crystallization of perovskite nickelate SmNiO 3 from amorphous Sm–Ni–O nanoparticles synthesized via laser ablation in liquids. These nanoparticles, with a mean diameter of ∼30 nm, were generated by laser ablation of sputtered amorphous Sm–Ni–O films and deposited onto grids specially conceived to allow for in situ heating during TEM observations. In situ heating to 600 °C (ramp rate 600 °C/s, 30 s hold) within the TEM revealed the emergence of crystallized SmNiO 3 domains, coexisting with secondary Sm 2 O 3 or NiO phases in particles exhibiting off-stoichiometric Sm/Ni ratios. High-resolution TEM, fast Fourier transforms, and energy-dispersive X-ray spectroscopy demonstrated that initial chemical composition, rather than particle size, dictates phase evolution: near-stoichiometric particles form predominantly SmNiO 3, whereas Sm- or Ni-rich particles undergo sequential crystallization of Sm 2 O 3 or NiO followed by SmNiO 3 nucleation. Core-loss electron energy-loss spectroscopy confirmed an order-of-magnitude increase in the Ni 3+ /Ni 2+ ratio upon annealing, signifying perovskite formation alongside residual Ni 2+ that can be attributed to oxygen vacancies or compositional inhomogeneities. A thermodynamic approach based on Gibbs free-energy landscapes rationalizes these pathways, and Gaussian fitting of SmNiO 3 grain sizes versus Ni content reveals maximum domain growth at ideal 1:1 Sm/Ni stoichiometry. These findings elucidate nanoscale crystallization mechanisms in strongly correlated oxide nanoparticles and offer a new potential route to integrating this material in new functional device architectures.
Language: English
Subfield: Biomedical Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: green
Awards: G1166465053, Isite LUE
OpenAlex ID: W4413369270